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Beilstein J. Org. Chem. 2017, 13, 564–570, doi:10.3762/bjoc.13.55
Graphical Abstract
Figure 1: A tripodal molecular pocket (a) [12] or jellyfish resembling receptors (b) [11,16].
Scheme 1: Example of Pd-catalyzed amination for modification of bile acid derivatives.
Scheme 2: Synthesis of 24-aminocholanols.
Scheme 3: Synthesis of 24-arylaminocholanols by Cu-catalyzed amination.
Scheme 4: Synthesis of 24-arylaminocholanols by Pd-catalyzed amination.
Figure 2: UV–vis spectra of 5c (50 μM solution in MeCN) before and after the addition of 5 equiv of metal per...